Facile fabrication of robust multilayer films: visible light-triggered chemical cross-linking by the catalysis of a ruthenium(II) complex.
نویسندگان
چکیده
Highly stable covalently attached multilayer films were constructed by visible-light irradiation of hydrogen-bonding directed multilayer films of poly(allylamine) and poly(4-vinylphenol).
منابع مشابه
Ruthenium(ii)-catalyzed olefination via carbonyl reductive cross-coupling† †Electronic supplementary information (ESI) available: Experimental details. See DOI: 10.1039/c7sc04207h
Natural availability of carbonyl groups offers reductive carbonyl coupling tremendous synthetic potential for efficient olefin synthesis, yet the catalytic carbonyl cross-coupling remains largely elusive. We report herein such a reaction, mediated by hydrazine under ruthenium(ii) catalysis. This method enables facile and selective cross-couplings of two unsymmetrical carbonyl compounds in eithe...
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 3 شماره
صفحات -
تاریخ انتشار 2011